Synonyms: (Dimethyl sulfide)trihydroboron; BMS; Borane-dimethyl sulfide
CAS Number: 13292-87-0
Formula: C2H9BS
Formula Weight: 75.97
Linear Formula: (CH3)2S · BH3
MDL No.: MFCD00013189
Density: 0.801 g/mL at 25 C(lit.)
Storage: 2-8C
Beilstein Registry Number: 3663489
EC Number: 236-313-6
UNSPSC Code: 12352000
Application: Reagent for hydroboration reduction and other applications.
Application: Used with a dendrimeric supported L-pyrrolidinol in the asymmetric reduction of indanones and tetralones. CBS-catalyzed asymmetric reduction of ferrocenyl-1,3-diketones to 1,3-diols. Highly enantioselective reduction of ketones catalyzed by C3-symmetric tripodal hydroxyamides.
Other Notes: 10.0-10.2 M as BH3. May contain excess methyl sulfide.
RIDADR: UN 3399A 4.3(3) / PGI
WGK Germany: 3
Flash Point(F): 64.4 F
Flash Point(C): 18 C
R Codes: 11-14/15-37/38-41
S Codes: 16-26-39-43
IOD Codes: F,Xi
Symbol: GHS02, GHS05, GHS06
Signal Word: Danger
Hazard Statements: H225-H260-H301 + H311-H315-H318-H335
Precautionary statements: P210-P231 + P232-P280-P301 + P310 + P330-P305 + P351 + P338 + P310-P370 + P378