CAS Number: 23719-80-4
Formula: C3H5BrMg
Formula Weight: 145.28
Linear Formula: C3H5BrMg
MDL No.: MFCD00672094
Boiling Point: 65 C
Density: 0.968 g/mL at 25 C
Storage: 2-8C
UNSPSC Code: 12352103
Application: Cyclopropylmagnesium bromide solution has been used in Grignard reaction that finds application as the key step in the preparation of aminopropylindenes, a chemotype of oxidosqualene cyclase (OSC) inhibitors from Grundmann′s ketone. It can react with trimethylborate to form cyclopropylboronic acid, which can undergo Suzuki-type coupling reactions with different aryl, and heteroaryl bromides to form the cyclopropyl adducts.
RIDADR: UN 3399BC 4.3(3) / PGII
WGK Germany: 3
Flash Point(F): 1.4 F
Flash Point(C): -17 C
R Codes: 11-14-19-34-37-40
S Codes: 16-26-36/37/39-45
IOD Codes: F,C
Symbol: GHS02, GHS05, GHS07, GHS08
Signal Word: Danger
Hazard Statements: H225-H261-H302-H314-H335-H351
Precautionary statements: P210-P231 + P232-P280-P370 + P378-P402 + P404-P403 + P235