Crystals of potassium chlorate belong to the monoclinic crystal system. On heating above 400C, it degrades to give potassium chloride and potassium perchlorate. It has strong oxidizing properties. On exposure to X-rays, oxygen-17 enriched KClO3 generates O3- radical, which was investigated by ESR (Electron Spin Resonance). Irradiation of potassium chlorate with X-ray causes the degradation to generate chloride, chlorite, hypochlorite and occluded oxygen. Significant quantities of dichlorine hexoxide and a trace of chlorine dioxide were also produced.
Molecular Formula: ClKO3
Molecular Weight: 122.55
Linear Structural Formula: KClO3
MDL Number: MFCD00011361
Purity: 99-101%
Melting Point: 356 C (lit.)
Application: Potassium chlorate may be used in the preparation of graphite oxide (GO).